Publications

2022

Visible-Light Enabled Late-Stage, Room-Temperature Aminocarbonylation of Aryl Iodides with Carbon Monoxide. Mühlfenzl, K. S., Sardana, M., Skrydstrup, T., Elmore, C. S. ChemistrySelect 2022, 7, e202203582.
Toward a Practical Catalyst for Convenient Deaminative Hydrogenation of Amides under Mild Conditions. Gausas, L., Jackstell, R., Skrydstrup, T., Beller, M. ACS Sustainable Chem. Eng. 2022, 10, 16046-16054.
Enriched amino acids. Neumann, K. T., Skrydstrup T. Nat. Chem. 2022, 14, 1339-1340.
The Investigation of a Switchable Irridium Catalyst for the Hydrogenation of Amides: A Case Study of C-O Versus C-N Scission. Ravn, A. K, Rezayee, N. M. ACS Catal. 2022, 12, 11927-11933.
tert-Amyl Alcohol Mediated Deconstruction of Polyurethane for Polyol and Aniline Recovery. Johansen, M. B., Donslund, B. S., Kristensen, S. K., Lindhardt, A. T., Skrydstrup, T. ACS Sustainable Chem. Eng. 2022, 10, 11191-11202.
A practical concept for catalytic carbonylations using carbon dioxide. Sang, R., Hu, Y., Razzaq, R., Mollaert, G., Atia, H., Bentrup, U., Sharif, M., Neumann, H., Junge, H., Jackstell R., Maes, B. U. W., Beller, M. Nat. Commun. 2022, 13, 4432.
Homogeneous Carbon Capture and Catalytic Hydrogenation: Toward a Chemical Hydrogen Battery System. Wei, D., Sang, R., Junge, H., Beller, M. JACS Au 2022, 2, 1020-1031.
Selective N-Terminal Acylation of Peptides and Proteins with Tunable Phenol Esters. Mikkelsen, J. H., Gustafsson, M. B. F., Skrydstrup, T., Jensen, K. B. Bioconjugate Chem. 2022, 33, 625-633.
Tuneable Phase, Morphology, and Performance of Bismuth Oxyhalide Photocatalysts via Microwave-Assisted Synthesis. Marks, M,, Jeppesen, H. S., Lock, N. ACS Appl. Mater. Interfaces 2022, 14, 23496-23506.
Pyrolysis of a metal-organic framework followed by in situ X-ray absorption spectroscopy, powder diffraction and pair distribution function analysis. Folkjær, M., Lundegaard, L. F., Jeppesen, H. S., Marks, M., Hvid, M. S., Frank, S., Cibin, G., Lock, N. Dalton Trans. 2022, 51, 10740-10750.
Pd-Catalyzed Difluoromethylation of Aryl Boronic Acids, Halides and Psudo Halides with Ex Situ Generated ICF₂H. Gedde, O. R., Bonde, A., Golbækdal, P. I., Skrydstrup, T. Chem. Eur. J. 28, 2022, e202200997.
Reduction of CO₂ to CO and Their Applications. Neumann, K. T., Ravn, A. K., Johansen, M. B., Donslund, A. S., Rønne, M. H., Gudmundsson, H. G., Skrydstrup, T. In The Chemical Transformations of C1 Compounds (eds K. Ding, X.-F. Wu, B. Han and Z. Liu). John Wiley & Sons, 2022, Vol. 3, Chapter 24, 1027-1073.
Revisiting Reduction of CO₂ to Oxalate with First-Row Transition Metals: Irreproducibility, Ambiguous Analysis, and Conflicting Reactivity. Marx, M., Frauendorf, H., Spannenberg, A., Neumann, H., Beller, M. JACS Au 2022, 2, 731-744..
New Phenol Esters for Efficient pH-Controlled Amine Acylation of Peptides, Proteins, and Sepharose Beads in Aqueous Media. Jensen, K. B., Mikkelsen, J. H., Jensen, S. P., Kidal, S., Friberg, G., Skrydstrup, T., Gustafsson, M. B. F. Bioconjugate Chem. 2022, 33, 172-179.

2021

Exploring the structures, stability, and light absorption properties of three thiostannates synthesised at similar conditions. Jeppesen, H. S., Nørby, P., Gammelgaard, J. J., Borup, K., Lock, N. Sci. Rep. 2021, 11, 22080.
Promoting Selective Generation of Formic Acid from CO₂ Using Mn(bpy)(CO)₃Br as Electrocatalyst and Triethylamine/Isopropanol as Additives. Madsen, M. R., Rønne, M. H., Heuschen, M., Golo, D., Ahlquist, M. S. G., Skrydstrup, T., Pedersen, S. U., Daasbjerg, K. J. Am. Chem. Soc. 2021, 143, 20491-20500.
Exploring the Influence of Atomic Level Structure, Porosity, and Stability of Bismuth(III) Coordination Polymers on Electrocatalytic CO₂ Reduction. Frank, S., Grape, E. S., Bøjesen, E. D., Larsen, R., Lamagni, P., Catalano, J., Inge, A. K., Lock, N. J. Matter. Chem. A 2021, 9, 26298-26310.
Regioselective Hydroalkylation of Vinylarenes via Cooperative Cu and Ni Catalysis. Ravn, A. K., Johansen, M. B., Skrydstrup. T. Angew. Chem. Int. Ed. 2022, 61, e202112390.

Nickel-Mediated Alkoxycarbonylation for Complete Carbon Isotope Replacement. Ton, S. J., Neumann, K. T., Nørby, P., Skrydstrup, T. J. Am. Chem. Soc. 2021, 143, 17816-17824.

Low-Valence Znδ+ (0<δ<2) Single-Atom Material as Highly Efficient Electrocatalyst for CO₂ Reduction. Li, S., Lu, X., Ceccato, M., Hu, X.-M., Roldan, A., Catalano, J., Liu, M., Skrydstrup, T., Daasbjerg, K. Angew. Chem. Int. Ed. 2021, 60, 22826-22832.

Mechanistic Elucidation of Dimer Formation and Strategies for Its Supression in Electrochemical Reduction of Fac-Mn(bpy)(CO)₃Br. Rønne, M. H., Madsen, M. R., Skrydstrup, T. Pedersen, S. U., Daasbjerg, K. ChemElectroChem 2021, 8, 2108-2114.

Evaluation of Manganese Catalysts for the Hydrogenative Deconstruction of Commercial and End-of-Life Polyurethane Samples. Gausas, L., Donslund, B. S., Kristensen, S. K., Skrydstrup, T. ChemSusChem 2021, 14, e202101705.

Practical Gas Cylinder-Free Preparation of Important Transition Metal-Based Precatalysts Requiring Gaseous Reagents. Sun, H., Ahrens, A., Kristensen, S. K., Gausas, L., Donslund, B. S., Skrydstrup, T. Org. Process Res. Dev. 2021, 25, 2300-2307.

Heteroleptic copper complexes with nitrogen and phosphorus ligands in photocatalysis: Overview and perspectives. Cortes, P. A. F., Marx, M., Trose, M., Beller M. Chem Catalysis, 2021, 1, 298-338.

Highly Scalable Conversion of Blood Protoporphyrin to an Efficient Electrocatalyst for CO₂-to-CO Conversion. Miola, M., Li, S., Hu, X.-M., Ceccato, M., Surkus, A. E., Welter, E., Pedersen, S. U., Junge, H., Skrydstrup, T., Beller, M., Daasbjerg, K. Adv. Mater. Interfaces 2021, 2100067.

On-Demand Synthesis of Phosphoramidites. Sandahl, A. F., Nguyen, T. J. D., Hansen, R. A., Johansen, M. B., Skrydstrup, T., Gothelf, K. G. Nat. Commun. 2021, 12, 2760.

Catalytic Hydrogenation of Polyurethane to Base Chemicals: From Model Systems to Commercial and End-of-Life Polyurethane Materials. Gausas, L., Kristensen, S. K., Sun, H., Ahrens, A., Donslund, B. S., Lindhardt, A. T., Skrydstrup. T. JACS Au 2021, 1, 517-524.

An amino-acid based system for CO2 capture and catalytic utilization to produce formates. Wei, D., Junge, H., Beller, M. Chem. Sci. 2021, 12, 6020-6024.

Are Amines the Holy Grail for Facilitating CO₂ reduction? Jakobsen, J. B., Rønne, M. H., Daasbjerg, K. Skrydstrup, T. Angew. Chem. Int. Ed. 2021, 60, 9174-9179.

Anion and Solvent Controlled Growth of Crystalline and Amorphous Zinc(II) Coordination Polymers and a Molecular Complex. Deville, C., Jeppesen, H. S., McKee, V., Lock, N. Dalton Trans. 2021, 50, 3979-3989.

Rapid Nickel(II)-Mediated Thiocarbonylation as a Direct Route to Isotopically Labeled Aliphatic Carboxamides. Pedersen, S., Donslund, A. S., Mikkelsen, J., Bakholm, O., Papp, F., Jensen, K., Gustafsson, M., Skrydstrup, T. Chem. Eur. J. 2021, 27, 7114-7123.

Design and Applications of a SO2 Surrogate in Palladium-Catalyzed Direct Aminosulfonylation between Aryl Iodides and Amines. Jia, X., Kramer, S., Skrydstrup, T. Lian, Z. Angew. Chem. Int. Ed. 2021, 60, 7353-7359.

Hydrophobic Copper Interfaces Boost Electroreduction of Carbon Dioxide to Ethylene in Water. Liang, H.-Q., Zhao, S., Hu, X.-M., Ceccato, M., Skrydstrup, T., Daasbjerg, K. ACS Catal. 2021, 11, 958-966.

Incorporation of Nickel Single Atoms into Carbon Paper as Self-Standing Electrocatalyst for CO₂ Reduction. Li, S., Ceccato, M., Lu, X., Frank, S., Lock, N., Roldan, A., Hu, X.-M., Skrydstrup, T., Daasbjerg, K. J. Mater. Chem. A 2021, 9, 1583-1592.

2020

Selective Catalytic Reduction of NO Using Phase-Pure Anatase, Rutile, and Brookite TiO₂ Nanocrystals. Yu, L., Godiksen, A. L., Mamahkel, A., Søndergaard-Pedersen, F., Rios-Carvajal, T., Marks, M., Lock, N., Rasmussen, S. B., Iversen B. B. Inorg. Chem. 2020, 59, 15324-15334.

Probing the validity of spinel inversion model: a combined SPXRD, PDF, EXAFS and NMR study of ZnAl₂O₄. Sommer, S., Bøjesen, E. D., Lock, N., Kasai, H., Skibsted, J., Nishibori, E., Iversen, B. B. Dalton Trans. 2020, 59, 13449-13461.

Achieving Near-Unity CO Selectivity for CO2 Electroreduction on an Iron-Decorated Carbon Material. Hu, X., Mendoza, D., Madsen, M. R., Joulié, D., Lassalle-Kaiser, B., Robert, M., Pedersen, S. U., Skrydstrup, T., Daasbjerg, K. ChemSusChem 2020, 13, 6360-6369.

Synthetic Developments on the Preparation of Sulfides from Thiol-Free Reagents. Batista, G. M. F., de Casto, P. P., dos Santos, J. A., Skrydstrup, T., Amarante, G. W. Org. Chem. Front. 2020, 8, 326-368.

Carbonylative Suzuki-Miyaura Couplings of Sterically Hindered Aryl Halides: Synthesis of 2-Aroylbenzoate Derivatives. Ismael, A., Skrydstrup, T., Bayer, A. Org. Biomol. Chem. 2020, 18, 1754-1759.

Stimuli-Responsive Degrafting of Polymer Brushes via Addressable Catecholato-Metal Attachments. Agergaard, A. H., Pedersen, S. U., Birkedal, H., Daasbjerg, K. Polym. Chem. 2020, 11, 5572-5577.

Silacarboxylic Acids as Bifunctional Reagents: Application in Palladium-Catalyzed External-CO-Free Carbonylative Cross-Coupling Reactions. Li, X., Xu, J., Li, Y., Kramer, S., Skrydstrup, T., Lian, Z. Adv. Synth. Catal. 2020, 362, 4078-4083.

Renewable Solvents for Palladium-Catalyzed Carbonylation Reactions. Ismael, A., Gevorgyan, A., Skrydstrup, T., Bayer, A. Org. Process Res. Dev. 2020, 24, 2665-2675.

Main Element Chemistry Enables Gas-Cylinder-Free Hydroformylations. Pedersen, S. K., Gudmundsson, H. G., Nielsen, D. U., Donslund, B. S., Hammershøj, H. C. D., Daasbjerg, K., Skrydstrup, T. Nature Catal. 2020, 3, 843-850.

Cubes on a String: A Series of Linear Coordination Polymers with Cubane-Like Nodes and Dicarboxylate Linkers. Deville, C., Folkjær, M., Reinholdt, P., Hvid, M. S., Lamagni, P., Borup, K., Sun, Z., Lauritsen, J. V., McKee, V., Jensen, K. M. Ø., Lock N. Nanoscale 2020, 12, 11601-11611.

Advantages in Using Inexpensive CO₂ to Favor Photocatalytic Oxidation of Benzylamines. Markushyna, Y., Lamagni, P., Catalano, J., Lock, N., Zhang, G., Antonietti, M., Savateev, A. ACS Catal. 2020, 10, 7336-7342.

Restructuring Metal–Organic Frameworks to Nanoscale Bismuth Electrocatalysts for Highly Active and Selective CO₂ Reduction to Formate. Lamagni, P., Miola, M., Hvid, M. S., Mamakhel, M. A. H., Christensen, M., Madsen, M. R., Jeppesen, H. S., Hu, X., Daasbjerg, K. Skrydstrup, T., Lock, N. Adv. Funct. Mater. 2020, 16, 1910408.

Controlled Release of Reactive Gases: A Tale of Taming Carbon Monoxide. Ravn, A. K., Johansen, M. B., Skrydstrup, T. ChemPlusChem 2020, 85, 1529-1533.

Access to Aryl and Heteroaryl Trifluoromethyl Ketones from Aryl Bromides and Fluorosulfates with Stoichiometric CO. Johansen, M. B., Gedde, O. R., Mayer, T. S., Skrydstrup, T. Org. Lett. 2020, 22, 4068-4072.

Evaluation of the Electrocatalytic Reduction of Carbon Dioxide using Rhenium and Ruthenium Bipyridine Catalysts Bearing Pendant Amines in the Secondary Coordination Sphere. Madsen, M. R., Jakobsen, J. B., Rønne, M. H., Liang, H., Hammershøj, H. C. D., Nørby, P., Pedersen, S. U., Skrydstrup, T., Daasbjerg, K. Organometallics 2020, 39, 1480-1490.

Stoichiometric Studies on the Carbonylative Trifluoromethylation of Aryl Pd(II) Complexes using TMSCF3 as the Trifluoromethyl Source. Domino, K., Johansen, M. B., Daasbjerg, K., Skrydstrup, T. Organometallics 2020, 39, 688-697.

Ligand Controlled Product Selectivity in the Electrochemical Carbon Dioxide Reduction Using Manganese Bipyridine Catalysts. Rønne, M. H. H., Cho, D., Madsen, M. R., Jakobsen, J. B., Eom, S., Escoudé, E., Hammershøj, H. C. D., Nielsen, D. U., Pedersen, S. U., Baik, M.-H., Skrydstrup, T., Daasbjerg, K. J. Am. Chem. Soc. 2020, 142, 4265-4275.

Direct Access to Isotopically Labeled Aliphatic Ketones Mediated by Nickel(I) Activation. Donslund, A. S., Pedersen, S. S., Gaardbo, C., Neumann, K. T., Kingston, L., Elmore, C. S., Skrydstrup, T. Angew. Chem. Int. Ed. 2020, 59, 8099-8103.

Adressing the Reproducibility of Photocatalytic Carbon Dioxide Reduction. Marx, M., Mele, A., Spannenberg, A., Steinlechner, C., Junge, H., Schollhammer, P., Beller, M. ChemCatChem 2020, 12, 1603-1608.

2019

Carbon Isotope Labeling Strategy for ß-Amino Acid Derivatives via Carbonylation of Azanickellacycles. Ravn, A. K., Vilstrup, M. B. T., Noerby, P., Nielsen, D. U., Daasbjerg, K. & Skrydstrup, T. J. Am. Chem. Soc. 2019, 141, 11821-11826.

Access to β-Ketonitriles via Nickel-Catalyzed Carbonylative Coupling of α-Bromonitriles with Alkylzinc Reagents. Donslund, A. S., Neumann, K. T., Corneliussen, N., Grove, E., Herbstritt, D., Daasbjerg, K. & Skrydstrup, T. Chem. Eur. J. 2019, 25, 9856-9860.

COtab: Expedient and Safe Setup for Pd-Catalyzed Carbonylation Chemistry . Collin, H., Reis, W., Nielsen, D. U., Lindhardt, A. T., Valle, M., Freitas, R. & Skrydstrup, T. Org. Lett. 2019, 21, 5775-5778.

Liquid Marbles: A Promising and Versatile Platform for Miniaturized Chemical Reactions. Xin, Z., Skrydstrup, T. Angew. Chem. Int. Ed. 2019, 58, 11952-11954.

Supported molecular catalysts for the heterogeneous CO2 electroreduction. Hu, X., Pedersen, S. U., Daasbjerg, K. Curr. Opin. Electrochem. 2019, 15, 148-154.

Molecular catalyst converts carbon dioxide to methanol. Hu, X., Daasbjerg, K. Nature 2019, 575, 598-599.

Two-phase bipolar electrografting. Madsen, M. R., Koefoed, L., Jensen, H., Daasbjerg, K., Pedersen, S. U. Electrochim. Acta 2019, 317, 61-69.

Electrochemical grafting of heterocyclic molecules on glassy carbon and platinum using heteroaromatic iodonium salts or iodo-substituted heteroaromatics. Sommerfeldt, A., Pedersen, S. U., Daasbjerg, K. Electrochim. Acta 2019, 261, 356-364.

Boosting Photocatalytic Hydrogen Production by Modulating Recombination Modes and Proton Adsorption Energy. Dai, Y., Bu, O., Sooriyagoda, R., Tavadze, P., Pavlic, O., Lim, T., Shen, Y., Mamakhel, A.,Wang, X., Li, Y., Niemantsverdriet, H., Iversen, B. B., Besenbacher, F., Xie, T., Lewis, J. P., Bristow, A. D., Lock, N., Su, R. J. Phys. Chem. Lett. 2019, 10, 5381-5386.

Solid Bi24O31Br10(OH)δ with Active Lattice Oxygen for the Efficient Photo-Oxidation of Primary Alcohols to Aldehydes. Dai, Y., Ren, P., Li, Y., Lv, D., Shen, Y., Li, Y., Niemantsverdriet, H., Besenbacher, F., Xiang, H., Hao, W., Lock, N., Wen, X., Lewis, J. P., Su, R. Angew. Chem. Int. Ed. 2019, 131, 6265-6270.

Structural changes during water-mediated amorphization of semiconducting two-dimensional thiostannates. Hvid, M. S., Jeppesen, H. S., Miola, M., Lamagni, P., Su, R., Jensen, K. M. Ø., Lock, N. IUCrJ, 2019, 6, 804-814.

Carbon nitride photocatalyzes regioselective aminium radical addition to the carbonyl bond and yields N-fused pyrroles. Kurpil, B., Otte, K., Mishchenko, A., Lamagni, P., Lipiński, W., Lock, N., Antonietti, M., Savateev, A. Nat. Commun. 2019, 10.

Green radicals of potassium poly(heptazine imide) using light and benzylamine. Markushyna, Y., Lamagni, P., Teutloff, C., Catalano, J., Lock, N., Guigang, G., Antonietti, M., Savateev, A. J. Mater. Chem. 2019, 7, 24771-24775.

Identification and Directed Development of Non‐Organic Catalysts with Apparent Pan‐Enzymatic Mimicry into Nanozymes for Efficient Prodrug Conversion. Walther, R., Winther, A., Fruergaard, A. S., van den Akker, W., Sørensen, L., Nielsen, S. M., Olesen, M. T. J., Dai, Y., Jeppesen, H. S., Lamagni, P., Savateev, A., Pedersen, S. L., Frich, C. K., Vigier, C. A., Lock, N., Singh, M.,Bansal, V., Meyer, R. L., Zelikin, A. N. Angew. Chem. Int. Ed. 2019, 58, 278-282.

Homogeneous Catalytic Hydrogenation of CO2 to Methanol - Improvements with Tailored Ligands. Scharnagl, F. K., Hertrich, M. F., Neitzel, G., Jackstell, R., Beller, M. Adv. Syn. Catal. 2019, 361, 374-379.

Improving Selectivity and Activity of CO2 Reduction Photocatalysts with Oxygen. Kreft, S., Schoch, R., Schneidewind, J., Rabeah, J., Kondratenko, E. V., Kondratenko, V. A., Junge, H., Bauer, M., Wohlrab, S., Beller, M. Chem 2019, 5, 1818-1833.

Mechanism and Scope of Nickel-Catalyzed Decarbonylative Borylation of Carboxylic Acid Fluorides. Malapit, C., Bour, J. R., Laursen, S. R., Sanford, M. S. J. Am. Chem. Soc. 2019, 141, 17322-17330.

2018

Ex Situ Formation of Methanethiol: Application in the Gold(I)-Promoted Anti-Markovnikov Hydrothiolation of Olefins. Kristensen, S. K., Laursen, S. L. R., Taarning, E. & Skrydstrup, T. Angew. Chem. Int. Ed. 2018, 57, 13887-13891.

Synthesis of Aliphatic Carboxamides Mediated by Nickel NN₂-Pincer Complexes and Adaption to Carbon Isotope-Labeling. Neumann, K. T., Donslund, A. S., Andersen, T., Nielsen, D. U. & Skrydstrup, T. Chem. Eur. J. 2018, 24, 14946-14949.

Chemically and electrochemically catalysed conversion of CO₂ to CO with follow-up utilization to value-added chemicals. Nielsen, D. U., Hu, X., Daasbjerg, K. & Skrydstrup, T. Nat. Catal. 2018, 1, 244–254.

Direct Access to Aryl Bis(trifluoromethyl)carbinols from Aryl Bromides or Fluorosulfates: Palladium-Catalyzed Carbonylation. Domino, K., Veryser, C., Wahlqvist, B. A., Gaardbo, C., Neumann, K. T., Daasbjerg, K. & Skrydstrup, T. Angew. Chem. Int. Ed. 2018, 57, 6858-6862.

Facile Synthesis of Iron- and Nitrogen-Doped Porous Carbon for Selective CO₂ Electroreduction. Shi, J-J., Hu, X-M., Madsen, M. R., Lamagni, P., Bjerglund, E. T., Pedersen, S. U., Skrydstrup, T. & Daasbjerg, K. ACS Appl. Nano Mater. 2018, 1, 3608-3615.

Intermittent, low dose carbon monoxide exposure enhances survival and dopaminergic differentiation of human neural stem cells. Dreyer-Andersen, N., Almeida, A. S., Jensen, P., Kamand, M., Okarmus, J., Rosenberg, T., Friis, S. D., Serrano, A. M., Blaabjerg, M., Kristensen, B. W., Skrydstrup, T., Gramsbergen, J. B., Vieira, H. L. A. & Meyer, M. PLoS One, 2018, 13, e0191207.

Carbonylative Coupling of Alkyl Zinc Reagents with Benzyl Bromides Catalyzed by a Nickel/NN₂ Pincer Ligand Complex. Andersen, T. L., Donslund, A. S., Neumann, K. T. & Skrydstrup, T. Angew. Chem. Int. Ed. 2018, 57, 800-804.

Ligand-free gold nanoparticles supported on mesoporous carbon as electrocatalysts for CO₂ reduction . Miola, M., Hu, X. M., Brandiele, R., Bjerglund, E. T., Grønseth, D. K., Durante, C.,Pedersen, S. U., Lock, N., Skrydstrup, T. & Daasbjerg, K. Journal of CO2 Utilization, 2018, 28, 50-58.

New Directions in Transition Metal Catalyzed Carbonylation Chemistry . Nielsen, D. U., Neumann, K. T. & Skrydstrup, T. Chimia, 2018, 72, 606-609.

Palladium Catalyzed Carbonylative Coupling of Alkyl Boron Reagents with Bromodifluoroacetamides . Yin, H., Kumke, J. J., Domino, K. & Skrydstrup, T. ACS Catal. 2018, 8, 3853-3858.

Pd-catalyzed carbonylative alpha-arylation of azlactones: A formal four-component coupling route to alpha,alpha-disubstituted amino acids . Lobo, D. J. P., Nielsen, D. U., Amarante, G. & Skrydstrup, T. J. Catal. 2018, 364, 366–370.

Recent developments in carbonylation chemistry using [¹³C]CO, [¹¹C]CO, and [¹⁴C]CO. Nielsen, D. U., Neumann, K. T., Lindhardt, A. T. & Skrydstrup, T. J. Labelled Comp. Radiopharm. 2018, 61, 949-987.

Selective CO₂ Reduction to CO in Water using Earth-Abundant Metal and Nitrogen-Doped Carbon Electrocatalysts. Hu, X-M., Hval, H. H., Bjerglund, E. T., Dalgaard, K. J., Madsen, M. R., Pohl, M-M., Welter, E., Lamagni, P., Buhl, K. B., Bremholm, M., Beller, M., Pedersen, S. U., Skrydstrup, T. & Daasbjerg, K. ACS Catal. 2018, 8, 6255-6264.

Energy-harvesting bio-electro-dehalogenation for sustainable wastewater treatment. Huang, L., Zhang, Y., Hu, X., Hansen, H. C. B., Pedersen, S. U., Daasbjerg, K. Electrochim. Acta 2018, 290, 38-45.

Graphene inclusion controlling conductivity and gas sorption of metal–organic framework. Lamagni, P., Pedersen, B. L., Godiksen, A. L., Mossin, S., Hu, X., Pedersen, S. U., Daasbjerg, K., Lock, N. RSC Adv. 2018, 8, 13921-13932.

Electrochemical grafting of heterocyclic molecules on glassy carbon and platinum using heteroaromatic iodonium salts or iodo-substituted heteroaromatics. Sommerfeldt, A., Pedersen, S. U., Daasbjerg, K. Electrochim. Acta 2018, 261, 356-364.

Crystalline and magnetic structure-property relationship in spinel ferrite nanoparticles. Andersen, H. L., Saura-Múzquiz, M., Granados, C., Canévet, E., Lock, N., Christensen, M. Nanoscale 2018, 10, 14902-14914.

Light-tuned selective photosynthesis of azo- and azoxy-aromatics using graphitic C3N4. Dai, Y., Li, C., Shen, Y., Lim, T., Xu, J., Li, Y., Niemantsverdriet, H., Besenbacher, F., Lock, N., Su, R. Nat. Commun. 2018, 9.

Efficient Solar-Driven Hydrogen Transfer by Bismuth-Based Photocatalyst with Engineered Basic Sites. Dai, Y., Li, C., Shen, Y., Zhu, S., Hvid, M. S., Wu, L. C., Skibsted, J., Li, Y., Niemantsverdriet, H., Besenbacher, F., Lock, N., Su, R. J. Am. Chem. Soc. 2018, 140, 16711-16719.

Base-free nickel-catalysed decarbonylative Suzuki-Miyaura coupling of acid fluorides. Malapit, C. A., Bour, J. R., Brigham, C. E., Sanford, M. S. Nature 2018, 563, 100-104.

Structure activity relationsships in metal-organic framework catalysts for the continuous flow synthesis of propylene carbonate from CO2 and propylene oxide. James, B. R., Boissonnault, J. A., Wong-Foy, A. G., Matzger, A. J. Sanford, M. S. RSC Adv. 2018, 8, 2132-2137.

Organocatalyzed Decarboxylative Trichloromethylation of Morita-Baylis-Hillman Adducts in Batch and Continuous Flow. Enevoldsen, M. V., Overgaard, J., Pedersen, M. S., Lindhardt, A. T. Chem. Eur. J. 2018, 24, 1204-1208.

Nucleophilic Fluorination Facilitated by a CsF-CaF2 Paked Bed Reactor in Continuous Flow. Johansen, M. B., Lindhardt, A. T. Chem. Commun. 2018, 54, 825-828.

Studying the Morita-Baylis-Hillman Reaction in Continuous Flow Using Paked Bed Reactors. Verdier, R. A. T., Mikkelsen, J. H., Lindhardt, A. T. Org. Process Res. Dev. 2018, 22, 1524-1533.

Improved Saftey During Transfer of Pyrophoric tert-Butyllithium from Flasks with Protective Seals. Johansen, M. B., Kondrup, J. C., Hinge, M., Lindhardt, A. T. Org. Process Res. Dev. 2018, 22, 903-905.

2017

Access to Perfluoroalkyl-Substituted Enones and Indolin-2-ones via Multicomponent Pd-Catalyzed Carbonylative Reactions . Yin, H. & Skrydstrup, T. J. Org. Chem. 2017, 82, 6474-6481.

Efficient Water Reduction with sp³-sp³ Diboron(4) Compounds: Application to Hydrogenations, H-D Exchange Reactions and Carbonyl Reductions. Flinker, M., Yin, H., Juhl, R. W., Eikeland, E. Z., Overgaard, J., Nielsen, D. U. & Skrydstrup, T. Angew. Chem. Int. Ed. 2017, 56, 15910-15915.

Enhanced Catalytic Activity of Cobalt Porphyrin in CO₂ Electroreduction upon Immobilization on Carbon Materials. Hu, X., Rønne, M. H., Pedersen, S. U., Skrydstrup, T. & Daasbjerg, K. Angew. Chem. Int. Ed. 2017, 56, 6468-6472.

S calable carbon dioxide electroreduction coupled to carbonylation chemistry . Jensen , M. T., Rønne, M. H., Ravn, A. K., Juhl, R. W., Nielsen, D. U., Hu, X., Pedersen, S. U., Daasbjerg, K. & Skrydstrup, T. Nat. Commun. 2017, 8, 489.

Ex situ generation of stoichiometric HCN and its application in the Pd-catalysed cyanation of aryl bromides: evidence for a transmetallation step between two oxidative addition Pd-complexes . Kristensen, S. K., Eikeland, E. Z., Taarning, E., Lindhardt, A. T. & Skrydstrup, T. Chem. Sci. 2017, 8, 8094-8105.

Experimental and Theoretical Studies on the Reduction of CO₂ to CO with Chloro(methyl)disilane Components from the Direct Process. Flinker, M., Lopez, S., Nielsen, D. U., Daasbjerg, K., Jensen, F. & Skrydstrup, T. Synlett. 2017, 28, 2439-2444.

Utilizing Glycerol as an Ex Situ CO-source in Pd-Catalyzed Alkoxycarbonylation of Styrenes . Nielsen, D. B., Wahlqvist, B., Nielsen, D. U., Daasbjerg, K. & Skrydstrup, T. ACS Catal. 2017, 7, 6089–6093.

Palladium-Catalyzed Aminocarbonylation in Solid-Phase Peptide Synthesis: A Method for Capping, Cyclization, and Isotope Labeling. Skogh, A., Friis, S. D., Skrydstrup, T. & Sandström, A. Org. Lett. 2017, 19, 2873-2876.

Application of Methyl Bisphosphine-Ligated Palladium Complexes for Low Pressure N-¹¹C-Acetylation of Peptides. Andersen, T. L., Nordeman, P., Christoffersen, H. F., Audrain, H., Antoni, G. & Skrydstrup, T. Angew. Chem. Int. Ed. 2017, 56, 4549-4553.

Evidence for Single-Electron Pathways in the Reaction between Palladium(II) Dialkyl Complexes and Alkyl Bromides under Thermal and Photoinduced Conditions . Andersen, T., Kramer, S., Overgaard, J. & Skrydstrup, T. Organometallics, 2017, 36, 2058-2066.

Copper-Catalyzed Carboxylation of Hydroborated Disubstituted Alkenes and Terminal Alkynes With Cesium Fluoride. Juhl, M., Laursen, S., Huang, Y., Nielsen, D. U., Daasbjerg, K. & Skrydstrup, T. ACS Catal. 2017, 7, 1392-1396.

Synthesis and selective ²H-, ¹³C-, and ¹⁵N-labeling of the Tau protein binder THK-523. Neumann, K. T., Lindhardt, A. T., Bang-Andersen, B. & Skrydstrup, T. J. Labelled Comp. Radiopharm. 2017, 60, 30-35.

Efficient Graphene Production by Combined Bipolar Electrochemical Intercalation and High-Shear Exfoliation. Bjerglund, E., Kristensen, M. E. P., Stambula, S., Botton, G., Pedersen, S. U., Daasbjerg, K. ACS Omega 2017, 2, 6492-6499.

Hierarchical MoS2 nanosheets on flexible carbon felt as an efficient flow-through electrode for dechlorination. Huang, L., Pedersen, S. U., Bjerglund, E., Lamagni, P., Glasius, M., Hansen, H. C. B., Daasbjerg, K. Environ. Sci. Nano 2017, 4, 2286-2296.

Graphene oxide-mediated rapid dechlorination of carbon tetrachloride by green rust. Huang, L., Hansen, H. C. B., Daasbjerg, K. J. Hazard. Mater. 2017, 323, 690-697.

Covalent Modification of Glassy Carbon Surfaces by Electrochemical Grafting of Aryl Iodides. Koefoed, L., Pedersen, S. U., Daasbjerg, K. Langmuir 2017, 33, 3217-3222.

On the Kinetic and Thermodynamic Properties of Aryl Radicals Using Electrochemical and Theoretical Approaches. Koefoed, L., Vase, K. H., Stenlid, J. H., Brinck, T., Yoshimura, Y., Lund, H., Pedersen, S. U., Daasbjerg, K. ChemElectroChem 2017, 4, 3212-3221.

Bipolar electrochemistry — A wireless approach for electrode reactions. Koefoed, L., Pedersen, S. U., Daasbjerg, K. Curr. Opin. Electrochem. 2017, 2, 13-17.

Incorporation of CuO NPs into modified UiO-66-NH2 metal-organic frameworks (MOFs) with melamine for catalytic C-O coupling in the Ullmann condensation. Sadeghi, S., Jafarzadeh, M., Abbasi, A. R., Daasbjerg, K. New J. Chem. 2017, 41, 12014-12027.

Light absorption engineering of a hybrid (Sn3S72-)(n) based semiconductor - from violet to red light absorption. Hvid, M. S., Lamagni, P., Lock, N. Sci. Rep. 2017, 7.

The structure-directing amine changes everything. Filsø, M., Chaaban, I., Shehabi, A. A., Skibsted, J., Lock, N. Acta Crystallogr. B. 2017, 73, 931-940.

Pd-Catalyzed Decarbonylative Cross-Couplings of Aroyl Chlorides. Malapit, C. A., Ichiishi, N., Sanford, M. S. Org. Lett. 2017, 19, 4142-4145.

A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol. Anderez-Fernandez, M., Vogt, L. K., Fischer, S., Zhou, W., Jiao, H., Garbe, M., Elangovan, S., Junge, K., Junge, H., Ludwig, R., Beller, M. Angew. Chem. Int. Ed. 2017, 56, 559-562.

Low-Temperature Hydrogenation of Carbon Dioxide to Methanol with a Homogenous Cobalt Catalyst. Schneidewind, J., Adam, R., Baumann, W., Jackstell, R., Beller, M. Angew. Chem. Int. Ed. 2017, 56, 1890-1893.

Palladium- and Nickel-Catalyzed Decarbonylative C-S Coupling to Convert Thioesters to Thioethers. Ichiishi, N., Malapit, C. A., Wozniak, L., Sanford, M. S. Org. Lett. 2017, 20, 44-47.

2016

A Palladium-Catalyzed Double Carbonylation Approach to Isatins from 2-Iodoanilines . Laursen, S., Jensen, M. T., Lindhardt, A. T., Jacobsen, M. F. & Skrydstrup, T. Eur. J. Org. Chem. 2016, 10, 1881-1885.

Chemo- and Regioselective Ethynylation of Tryptophan-Containing Peptides and Proteins . Hansen, M. B., Hubalek, F., Skrydstrup, T. & Hoeg-Jensen, T. Chem. Eur. J. 2016, 22, 1572-1576.

Controlled electropolymerisation of a carbazole-functionalised iron porphyrin electrocatalyst for CO2 reduction . Hu, X., Salmi, Z., Lillethorup, M., Bjerglund Pedersen, E., Robert, M., Pedersen, S. U., Skrydstrup, T. & Daasbjerg, K. Chem. Commun. 2016, 52, 5864-5867.

Cooperative redox activation for carbon dioxide conversion . Lian, Z., Nielsen, D. U., Lindhardt, A. T., Daasbjerg, K. & Skrydstrup, T. Nat. Commun. 2016, 7, 13782.

Development of a Palladium-Catalyzed Carbonylative Coupling Strategy to 1,4-Diketones . Yin, H., Nielsen, D. U., Johansen, M. K., Lindhardt, A. T. & Skrydstrup, T. ACS Catal. 2016, 6, 2982-2987.

Direct Access to α,α-Difluoroacylated Arenes by Palladium-Catalyzed Carbonylation of (Hetero)Aryl Boronic Acid Derivatives. Andersen, T. L., Frederiksen, M. W. W., Domino, K. & Skrydstrup, T. (2016). Angew. Chem. Int. Ed. 2016, 55, 10396-10400.

Direct trans-Selective Ruthenium-Catalyzed Reduction of Alkynes in Two-Chamber Reactors and Continuous Flow. Neumann, K. T., Klimczyk, S., Burhardt, M., Bang-Andersen, B., Skrydstrup, T. & Lindhardt, A. T. ACS Catal. 2016, 6, 4710-4714.

How Glycosaminoglycans Promote Fibrillation of Salmon Calcitonin . Malmos, K. G., Bjerring, M., Jessen, C. M., Nielsen, E. H. T., Poulsen, E. T., Christiansen, G., Vosegaard, T., Skrydstrup, T., Enghild, J. J., Pedersen, J. S. & Otzen, D. E. J. Biol. Chem. 2016, 291, 16849-16862.

Incorporation of β-Silicon-β3-Amino Acids in the Antimicrobial Peptide Alamethicin Provides a 20-Fold Increase in Membrane Permeabilization. Madsen, J. L. H., Hjørringgaard, C. U., Vad, B. S., Otzen, D. & Skrydstrup, T. Chem. Eur. J. 2016, 22, 8358-8367.

Palladium-Catalyzed Carbonylative Synthesis of 2,3-Disubstituted Chromones. Shen, C., Li, W., Yin, H., Spannenberg, A., Skrydstrup, T. & Wu, X-F. Adv. Synth. Catal. 2016, 358, 466-479.

Palladium-Catalyzed Carbonylative α-Arylation of tert-Butyl Cyanoacetate with (Hetero)aryl Bromides . Jensen, M. T., Juhl, M., Nielsen, D. U., Jacobsen, M. F., Lindhardt, A. T. & Skrydstrup, T. J. Org. Chem. 2016, 81, 1358-1366.

Pd-Catalyzed Carbonylative Synthesis of Other-Membered Heterocycles from Aryl Halides. Nielsen, D. U., Lian, Z., Lindhardt, A. T. & Skrydstrup, T. In X-F. Wu & M. Beller (Eds.), Topics in Heterocyclic Chemistry: Transition Metal Catalyzed Carbonylative Synthesis of Heterocycles 2016, 42, 89-99.

The Development and Application of Two-Chamber Reactors and Carbon Monoxide Precursors for Safe Carbonylation Reactions . Friis, S. D., Lindhardt, A. T. & Skrydstrup, T. Acc. Chem. Res. 2016, 49, 594-605.

Tin-containing silicates: Identification of a glycolytic pathway via 3-deoxyglucosone . Tolborg, S., Meier, S., Sádaba, I., Elliot, S. G., Kristensen, S. K., Saravanamurugan, S., Riisager, A., Fristrup, P., Skrydstrup, T. & Taarning, E. Green Chem. 2016, 18, 3360-3369.

Hydrophilic Polymer Brush Layers on Stainless Steel Using Multilayered ATRP Initiator Layer. Friis, J. E., Brøns, K., Salmi, Z., Shimizu, K., Subbiahdoss, G., Holm, A. H., Santos, O., Pedersen, S. U., Meyer, R. L., Daasbjerg, K., Iruthayaraj, J. ACS Appl. Mater. Inter. 2016, 8, 30616-30627.

Grafting of Aryl Diazonium, Iodonium, and Sulfonium Salts in Unusual Patterns by Exploiting the Potential Gradient in Bipolar Electrochemistry. Koefoed, L., Pedersen, S. U., Daasbjerg, K. ChemElectroChem 2016, 3, 495-501.

Functionalizing Arrays of Transferred Monolayer Graphene on Insulating Surfaces by Bipolar Electrochemistry. Koefoed, L., Pedersen, E. B., Thyssen, L., Vinther, J., Kristiansen, T., Pedersen S. U., Daasbjerg, K. Langmuir 2016, 32, 6289-6296.

One-Step Preparation of Bifunctionalized Surfaces by Bipolar Electrografting. Koefoed, L., Shimizu, K., Pedersen, S. U., Daasbjerg, K., Kuhn, A., Zigah, D. RSC Adv. 2016, 6, 3882-3887.

Wohl-Ziegler Bromination of Electrografted Films for Optimizing Atom Transfer Radical Polymerization. Nielsen, S. U., Koefoed, L., Lund, H., Daasbjerg, K., Pedersen, S. U. Electroanalysis 2016, 28, 2849–2854.

Automated coating procedures to produce poly(ethylene glycol) brushes in fused-silica capillaries. Poulsen, N. N., Østergaard, J., Petersen, N. J., Daasbjerg, K., Iruthayaraj, J., Dedinaite, A., Makuska, R., Jensen, H. J. Sep. Sci. 2016, 40, 779–788.

Electroinduced Intercalation of Tetraalkylammonium Ions at the Interface of Graphene Grown on Copper, Platinum, and Iridium. Salmi, Z., Koefoed, L., Jensen, B. B. E., Cabo, A. G., Hofmann, P., Pedersen, S. U., Daasbjerg, K. ChemElectroChem 2016, 3, 2202–2211.

Electrochemical procedure for constructing poly(phenylene sulfide) brushes on glassy carbon and stainless steel. Shimizu, K., Blaikie, F. H., Kongsfelt, M., Sørensen, K. D. S., Pedersen, S. U., Daasbjerg, K. J. Polym. Sci. Pol. Chem. 2016, 54, 91-98.

Iron-Catalyzed Hydrogenation of Amides to Alcohols and Amines. Rezayee, N. M., Samblanet, D. C., Sanford, M. S. ACS Catal. 2016, 6, 6377-6383.

Selective catalytic two-step process for ethylene glycol from carbon monoxide. Dong, K., Elangovan, S., Sang, R., Spannenberg, A., Jackstell, R., Junge, K., Li, Y., Beller, M. Nat. Commun. 2016, 7.

Highly active and selective photochemical reduction of CO2 to CO using molecular-defined cyclopentadienone iron complexes. Rosas-Hernández, A., Alsabeh, P. G., Barsch, E., Junge, H., Ludwig, R., Beller, M. Chem. Commun. 2016, 52, 8393-8396.

2015

Access to 2-(Het)aryl and 2-Styryl Benzoxazoles via Palladium-Catalyzed Aminocarbonylation of Aryl and Vinyl Bromides . Neumann, K. T., Lindhardt, A. T., Bang-Andersen, B. & Skrydstrup, T. Org. Lett. 2015, 17, 2094-2097.

C–H Activation Dependent Pd-Catalyzed Carbonylative Coupling of (Hetero)Aryl Bromides and Polyfluoroarenes.Lian, Z., Friis, S. D. & Skrydstrup, T. Chem. Commun. 2015, 51, 1870-1873.

Efficient ¹¹C-carbonylation of isolated aryl palladium complexes for PET: Application to challenging radiopharmaceutical synthesis. Andersen, T. L., Friis, S. D., Audrain, H., Nordeman, P., Antoni, G. & Skrydstrup, T. J. Am. Chem. Soc. 2015, 137, 1548-1555.

General method for the preparation of active esters by palladium-catalyzed alkoxycarbonylation of aryl bromides. De Almeida, A. M., Andersen, T. L., Lindhardt, A. T., De Almeida, M. V. & Skrydstrup, T. J. Org. Chem. 2015, 80, 1920-1928.

Organocatalyzed CO₂ trapping using alkynyl indoles. Xin, Z., Lescot, C., Friis, S. D., Daasbjerg, K. & Skrydstrup, T. Angew. Chem. Int. Ed. 2015, 54, 6862-6866.

Palladium-Catalyzed Carbonylative Couplings of Vinylogous Enolates: Application to Statin Structures. Makarov, I. S., Kuwahara, T., Jusseau, X., Ryu, I., Lindhardt, A. T. & Skrydstrup, T. J. Am. Chem. Soc. 2015, 137, 14043-14046.

Palladium-catalysed carbonylative α-arylation of nitromethane. Lian, Z., Friis, S. D. & Skrydstrup, T. Chem. Commun. 2015, 51, 3600-3603.

Patterned Carboxylation of Graphene Using Scanning Electrochemical Microscopy. Torbensen, K., Kongsfelt, M., Shimizu, K., Bjerglund Pedersen, E., Skrydstrup, T., Pedersen, S. U. & Daasbjerg, K. Langmuir, 2015, 31, 4443-4452.

Pd-Catalyzed Carbonylative Access to Aroyl Phosphonates from (Hetero)Aryl Bromides. Lian, Z., Yin, H., Friis, S. D. & Skrydstrup, T. Chem. Commun. 2015, 51, 7831-7834.

Rapid and Efficient Conversion of ¹¹CO₂ to ¹¹CO through Silacarboxylic Acids: Applications in Pd-Mediated Carbonylations. Nordeman, P., Friis, S. D., Andersen, T. L., Audrain, H., Larhed, M., Skrydstrup, T. & Antoni, G. Chem. Eur. J. 2015, 21, 17601-17604.

Scaffolded multimers of hIAPP20-29 peptide fragments fibrillate faster and lead to different fibrils compared to the free hIAPP20-29 peptide fragment. Christoffersen, H. F., Andreasen, M., Zhang, S., Nielsen, E. H., Christiansen, G., Dong, M., Skrydstrup, T. & Otzen, D. E. BBA-Proteins Proteom. 2015, 1854, 1890-1897.

Synthesis of acyl carbamates via four component Pd-catalyzed carbonylative coupling of aryl halides, potassium cyanate, and alcohols . Yin, H., de Almeida, A. M., De Almeida, M. V., Lindhardt, A. T. & Skrydstrup, T. Org. Lett. 2015, 17, 1248-1251.

The natural, peptaibolic peptide SPF-5506-A4 adopts a β-bend spiral structure, shows low hemolytic activity and targets membranes through formation of large pores. Frahm, H., Hansen, S. K., Vad, B. S., Nielsen, E. H., Nielsen, J. T., Vosegaard, T., Skrydstrup, T. & Otzen, D. E. BBA-Proteins Proteom. 2015, 1854, 882-889.

Revised 21.12.2022

Karoline Thorum Neumann

Interdisciplinary Nanoscience Center

CADIAC

Publications