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Jørgen Skibsted


Keywords

  • Solid-State NMR
  • Portland Cement
  • CO2 Emission
  • Heterogeneous Catalysis
  • Materials Research

Head of Solid-State NMR Spectroscopy Group

Professor Jørgen Skibsted
PhD in Chemistry

From order to disorder

A principal goal of our research is to explore structure and reactivity of cementitious materials, mainly by solid-state nucleic magnetic resonance (NMR) techniques, and to utilize this information in the development of the next generation of sustainable cement-based materials. The reactivity can often be significantly increased by introducing structural disorder in the materials.

Our research focuses on the application of solid-state NMR spectroscopy in inorganic materials research. The main areas are cement-based materials, heterogeneous catalysts, inorganic framework structures, glasses, and new materials for hydrogen storage. Our principal field is cement-based materials. In this field, academia and industry face the global challenge of developing more sustainable cement production, since today’s production is responsible for roughly 5% of the total anthropogenic CO2 emissions. We contribute to this task by the development of new cement binders based on alkali-activated systems and new supplementary cementitious materials (SCMs) which can partly replace the CO2-intensive Portland clinkers in cement blends. A main advantage of solid-state NMR is the equal detection of crystalline and amorphous materials. This is utilized to study disorder in the SCMs introduced either by guest-ion incorporation or thermal treatment procedures.

Our current research in both cementitious materials and heterogeneous catalysts involve collaborations with national and international industrial and academic partners.

Recent publications

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Kucharczyk, S., Zajac, M., Stabler, C., Thomsen, R. M., Ben Haha, M., Skibsted, J. & Deja, J. (2019). Structure and reactivity of synthetic CaO-Al2 O3 -SiO2 glasses. Cement and Concrete Research, 120, 77-91. https://doi.org/10.1016/j.cemconres.2019.03.004
Shi, Z., Ferreiro, S., Lothenbach, B., Geiker, M. R., Kunther, W., Kaufmann, J., Herfort, D. & Skibsted, J. (2019). Sulfate resistance of calcined clay – Limestone – Portland cements. Cement and Concrete Research, 116, 238-251. https://doi.org/10.1016/j.cemconres.2018.11.003
Molino, A., Holzinger, J., Lukaszuk, K. A., Rojo-Gama, D., Gunnaes, A. E., Skibsted, J., Lundegaard, L. F., Svelle, S., Beato, P., Bordiga, S. & Lillerud, K. P. (2019). Synthesis of ZSM-23 (MTT) zeolites with different crystal morphology and intergrowths: effects on the catalytic performance in the conversion of methanol to hydrocarbons. Catalysis Science & Technology, 9(23), 6782-6792. https://doi.org/10.1039/c9cy01068h
Le, T. T., Pistidda, C., Puszkiel, J., Castro Riglos, M. V., Karimi, F., Skibsted, J., Gharibdoust, S. P., Richter, B., Emmler, T., Milanese, C., Santoru, A., Hoell, A., Krumrey, M., Gericke, E., Akiba, E., Jensen, T. R., Klassen, T. & Dornheim, M. (2018). Design of a Nanometric AlTi Additive for MgB2-Based Reactive Hydride Composites with Superior Kinetic Properties. Journal of Physical Chemistry C, 122(14), 7642-7655. https://doi.org/10.1021/acs.jpcc.8b01850