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Jørgen Skibsted


Keywords

  • Solid-State NMR
  • Portland Cement
  • CO2 Emission
  • Heterogeneous Catalysis
  • Materials Research

Head of Solid-State NMR Spectroscopy Group

Professor Jørgen Skibsted
PhD in Chemistry

From order to disorder

A principal goal of our research is to explore structure and reactivity of cementitious materials, mainly by solid-state nucleic magnetic resonance (NMR) techniques, and to utilize this information in the development of the next generation of sustainable cement-based materials. The reactivity can often be significantly increased by introducing structural disorder in the materials.

Our research focuses on the application of solid-state NMR spectroscopy in inorganic materials research. The main areas are cement-based materials, heterogeneous catalysts, inorganic framework structures, glasses, and new materials for hydrogen storage. Our principal field is cement-based materials. In this field, academia and industry face the global challenge of developing more sustainable cement production, since today’s production is responsible for roughly 5% of the total anthropogenic CO2 emissions. We contribute to this task by the development of new cement binders based on alkali-activated systems and new supplementary cementitious materials (SCMs) which can partly replace the CO2-intensive Portland clinkers in cement blends. A main advantage of solid-state NMR is the equal detection of crystalline and amorphous materials. This is utilized to study disorder in the SCMs introduced either by guest-ion incorporation or thermal treatment procedures.

Our current research in both cementitious materials and heterogeneous catalysts involve collaborations with national and international industrial and academic partners.

Recent publications

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Jakobsen, H. J., Bildsøe, H. K., Skibsted, J., Hansen, M. R., Brorson, M., Srinivasan, B. R., Srinivasan, B. R. & Bensch, W. (2009). Site Preferences of NH4+ in Its Solid Solutions with Cs2WS4 and Rb2WS4 from 14N, 33S, 87Rb, and 133Cs MAS NMR. Poster session presented at 50th Experimental NMR Conference, Asilomar, Pacific Groove, California, United States.
Lindgreen, H., Geiker, M., Krøyer, H., Springer, N. & Skibsted, J. (2008). Microstructure engineering of Portland cement pastes and mortars through addition of ultrafine layer silicates. Cement and Concrete Composites, 30, 686-699.
Bomholdt Ravnsbæk, D., Skibsted, J., Cerenius, Y. & Jensen, T. R. (2008). New alkali zinc tetrahydridoboranates. Poster session presented at MH2008, Reykjavik, Iceland.