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Jørgen Skibsted


Keywords

  • Solid-State NMR
  • Portland Cement
  • CO2 Emission
  • Heterogeneous Catalysis
  • Materials Research

Head of Solid-State NMR Spectroscopy Group

Professor Jørgen Skibsted
PhD in Chemistry

From order to disorder

A principal goal of our research is to explore structure and reactivity of cementitious materials, mainly by solid-state nucleic magnetic resonance (NMR) techniques, and to utilize this information in the development of the next generation of sustainable cement-based materials. The reactivity can often be significantly increased by introducing structural disorder in the materials.

Our research focuses on the application of solid-state NMR spectroscopy in inorganic materials research. The main areas are cement-based materials, heterogeneous catalysts, inorganic framework structures, glasses, and new materials for hydrogen storage. Our principal field is cement-based materials. In this field, academia and industry face the global challenge of developing more sustainable cement production, since today’s production is responsible for roughly 5% of the total anthropogenic CO2 emissions. We contribute to this task by the development of new cement binders based on alkali-activated systems and new supplementary cementitious materials (SCMs) which can partly replace the CO2-intensive Portland clinkers in cement blends. A main advantage of solid-state NMR is the equal detection of crystalline and amorphous materials. This is utilized to study disorder in the SCMs introduced either by guest-ion incorporation or thermal treatment procedures.

Our current research in both cementitious materials and heterogeneous catalysts involve collaborations with national and international industrial and academic partners.

Recent publications

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Scrivener, K. L., Lothenbach, B., De Belie, N., Gruyaert, E., Skibsted, J., Snellings, R. & Vollpracht, A. (2015). TC 238-SCM: hydration and microstructure of concrete with SCMs: State of the art on methods to determine degree of reaction of SCMs. Materials and Structures, 48(4), 835-862. https://doi.org/10.1617/s11527-015-0527-4
Saldan, I., Schulze, M., Pistidda, C., Gosalawit-Utke, R., Zavorotynska, O., Rude, L. H., Skibsted, J., Haase, D., Cerenius, Y., Jensen, T. R., Spoto, G., Baricco, M., Taube, K. & Dornheim, M. (2013). Hydrogen sorption in the LiH-LiF-MgB2 system. The Journal of Physical Chemistry Part C, 117(33), 17360-17366. https://doi.org/10.1021/jp405856s
Ruiz-Santaquiteria, C., Skibsted, J., Fernández-Jiménez, A. & Palomo, A. (2012). Alkaline solution/binder ratio as a determining factor in the alkaline activation of aluminosilicates. Cement and Concrete Research, 42(9), 1242-1251. https://doi.org/10.1016/j.cemconres.2012.05.019
Ruiz-Santaquiteria, C. & Skibsted, J. (2018). Identification of reactive sites in calcined kaolinite and montmorillonite from a combination of chemical methods and solid-state nmr spectroscopy. In F. Martirena , A. Favier & K. Scrivener (Eds.), Calcined Clays for Sustainable Concrete - Proceedings of the 2nd International Conference on Calcined Clays for Sustainable Concrete (Vol. 16, pp. 404-408). Springer. https://doi.org/10.1007/978-94-024-1207-9_65
Rude, L. H., Hino, S., Hauback, B. C., Besenbacher, F., Skibsted, J. & Jensen, T. R. (2012). Improving the decomposition kinetics of metal borohydrides. Poster session presented at Asian Symposium on Hydrogen Storage Materials, 2012, Korea, Republic of.