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Jørgen Skibsted


Keywords

  • Solid-State NMR
  • Portland Cement
  • CO2 Emission
  • Heterogeneous Catalysis
  • Materials Research

Head of Solid-State NMR Spectroscopy Group

Professor Jørgen Skibsted
PhD in Chemistry

From order to disorder

A principal goal of our research is to explore structure and reactivity of cementitious materials, mainly by solid-state nucleic magnetic resonance (NMR) techniques, and to utilize this information in the development of the next generation of sustainable cement-based materials. The reactivity can often be significantly increased by introducing structural disorder in the materials.

Our research focuses on the application of solid-state NMR spectroscopy in inorganic materials research. The main areas are cement-based materials, heterogeneous catalysts, inorganic framework structures, glasses, and new materials for hydrogen storage. Our principal field is cement-based materials. In this field, academia and industry face the global challenge of developing more sustainable cement production, since today’s production is responsible for roughly 5% of the total anthropogenic CO2 emissions. We contribute to this task by the development of new cement binders based on alkali-activated systems and new supplementary cementitious materials (SCMs) which can partly replace the CO2-intensive Portland clinkers in cement blends. A main advantage of solid-state NMR is the equal detection of crystalline and amorphous materials. This is utilized to study disorder in the SCMs introduced either by guest-ion incorporation or thermal treatment procedures.

Our current research in both cementitious materials and heterogeneous catalysts involve collaborations with national and international industrial and academic partners.

Recent publications

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Vigna, E. & Skibsted, J. (2015). Optimization of alkali activated Portland cement – calcined clay blends based on the phase assemblage in the Na2O-CaO-Al2O3-SiO2-H2O system. In K. Scrivener & A. Favier (Eds.), Calcined Clays for Sustainable Concrete: Proceedings of the 1st International Conference on Calcined Clays for Sustainable Concrete (pp. 101-107). Springer. https://doi.org/10.1007/978-94-017-9939-3_13
Dai, Z., Kunther, W., Ferreiro, S., Herfort, D. & Skibsted, J. (2015). Phase assemblages in hydrated Portland cement, calcined clay and limestone blends from solid-state 27Al and 29Si MAS NMR, XRD, and thermodynamic modeling. In K. Scrivener & A. Favier (Eds.), Calcined Clays for Sustainable Concrete: Proceedings of the 1st International Conference on Calcined Clays for Sustainable Concrete (pp. 109-115). Springer. https://doi.org/10.1007/978-94-017-9939-3_14
Garg, N., Enemark-Rasmussen, K., Dai, Z. & Skibsted, J. (2015). Pozzolanic reactivity of thermally activated kaolinite and montmorillonite in Portland cement blends and their impact on the formed C-S-H phase. In ICCC 2015 Beijing : the 14th international congress on the chemistry of cement, 13-16 October, 2015: Abstract Book vol. 1 (pp. 272)